Dr. B. D. Gupta
Professor, Department of Chemistry
Indian Institute of Technology
Kanpur - 208016, UP, India

email: bdg@iitk.ac.in

 

 

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Recent Publications:

1.      Hindered rotation leading to nonequivalence in 2-substituted benzyl cobaloximes: Structure-property relationship, Debaprasad Mandal, and B. D. Gupta, Organometallic 26 (2007) 658-670, DOI: 10.1021/om060940d

2.      The interaction between axial and equatorial ligands in cobaloximes: NMR changes, Debaprasad Mandal, Preeti Chadha, Moitree Laskar, Mouchumi Bhuyan, B. D. Gupta, Tet. Lett 48 (2007) 2377-2379

3.      Co-C Bond homolysis: Reactivity difference between alkyl and benzyl cobaloximes, Debaprasad Mandal, Mouchumi Bhuyan, Moitree Laskar, B. D. Gupta, Organometallic (2007) 2795-2798

4.     Co-C Bond reactivity and cis influence relationship in benzylcobaloximes with glyoxime and dimesitylglyoxime. Mouchuni Bhuyan, Moitree Laskar, Debaprasad Mandal, B. D. Gupta, Organometallics  (2007)  3559-356 .

5.     Cobaloximes with Pyrazine and Their Bimetallic Complexes, Debaprasad Mandal and B. D. Gupta, Eur.J. Inorg. Chem., (2006) 4086–4095

6.      Hindered rotation leading to nonequivalence in cobaloximes, Debaprasad Mandal and B. D. Gupta, Organometallics, 25 (2006) 3305-3307

7.      Cobaloximes with mixed dioximes of glyoxime and diphenylglyoxime: synthesis, characterization, CV, X-ray studies and crystal packing, B. D. Gupta, R. Yamuna and Debaprasad Mandal, Orgaometallics 25 (2006) 706–714

8.      Sulfur Dioxide Insertion Into Co−C Bond In Organocobaloximes: Crystal Structure And Co−C Bond Reactivity Study, Preeti Chadha, B. D. Gupta and Kingsuk Mahata, Organometallics, 25 (2006) 92–98

9.      2-Substituted m-Xylylene Bridged Dicobaloximes: Structure-Property Relationship Using Variable Temperature 1H NMR Study V. Vijaikanth, B. D. Gupta, Debaprasad Mandal and Shashank Shekhar , Organometallics, 24 (2005) 4454-4460

10.  Pyrazine Bridged Benzyl Dicobaloximes: Competition between π-Interaction and Steric   Crowding in Crystal Structure, Debaprasad Mandal and B. D. Gupta, J. Organometal. Chem, 690 (2005) 3746-3754.

11.  Cobaloximes with Dimesitylglyoxime: Synthesis, Characterization, and Spectral     Correlations with the Related Cobaloximes, Debaprasad Mandal and B. D. Gupta, Organometallics, 24 (2005) 1501-1510.

12.  Synthesis characterization, and Variable-Temperature 1H NMR Behavior of      Organo-Bridged Dicobaloximes. B. D. Gupta, V. Vijaikanth, Veena Singh, Organometallics, 23 (2004) 2067-2079.

13.  Reaction of organocobaloximes with aryldisulfonyl chlorides, B. D. Gupta, V. Vijaikanth, J. Organometal. Chem., 689 (2004) 1102-1109.

14.  Organocobaloximes with Mixed Dioxime equatorial Ligands: A Convenient One-Pot Synthesis. X-ray Structures and Cis-Trans Influence Studies, B. D. Gupta, Veena Singh, R. Yamuna, T. Barclay and W. Cordes, Organometallics, 22 (2003) 2670-2678.

15.  Synthesis, characterisation, cis-trans influence in cobaloximes with glyoxime as the equatorial ligand, B. D. Gupta, R. Yamuna, Veena Singh and Usha Tiwari, Organometallics, 22 (2003) 226-232



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