Dr. B. D. Gupta
Professor, Department of Chemistry
Indian Institute of Technology
Kanpur - 208016, U.P, India
email: bdg@iitk.ac.in

 

 

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Complete List of publications:

M.S. (Hons)

  • Hexa Co-ordinated complexes of phenyl(methyl/benzyl) tin dichlorides with nitrogen donors, K.L.Jaura, J.S.Khurana, V.K.Verma and B.D.Gupta, B.D.Gupta, Ind. J. Chem., 48,1972,537-42
  • Adducts of alkyl/aralkyl tin dichlorides with bidentate ligands, K.L.Jaura, S.K.Bhalla, B.D.Gupta and V.K.Verma, Ind. J. Chem., 11,1973,49-52

Ph.D.

  • Substituent effects:Polar and pi electron substituent effects by 19F NMR , W.Adcock, M.J.S Dewar and B.D. Gupta, J. Am. Chem. Soc., 95,1973,7353-7358
  • Carbon magnetic resonance of organometallic compounds: Hyperconjugative effects in benzyl silanes, S.Q.A.Rizvi, B.D. Gupta, W. Adcock and W. Kitching, J. Organomet. Chem., 63, 1973,67-77
  • 13C NMR of organometallic compounds: Phenyl and benzyl trimethyl stannanes and related compounds, D. Doddrell, M.L.Bullpit, C.J. Moore, C.W. Fong, W. Kitching and B.D. Gupta, Tet. Lett, 1973,665
  • Concerning the 13C chemical shifts of benzocycloalkenes, W. Adcock, B.D. Gupta, T.C. Khor, D. Doddrell, D. Jordan and W. kitching, J. Am. Chem. Soc., 96,1974, 1595-97
  • Conformational consequences of metallomethyl interactions: A 13C study W.Adcock, B.D.Gupta, W.Kitching and D.Doddrell, J.Am.Chem.Soc 96, 1974, 7360-61
  • Polar field effects of 19F chemical shifts: an important effect W.Adcock and B.D.Gupta, J.Am.Chem.Soc., 97,1975, 6871-72
  • Conformational consequences of metallomethyl interactions: A 13C study W. Adcock, B.D. Gupta, W. Kitching and D. Doddrell, J. Organometal.chem., 102, 1975,297-311
  • The electronic effect of substituted methyl groups. A 13C NMR study W.Adcock, B.D. Gupta and W. Kitching, J. Org. Chem., 41,1976,1498-1504
  • 13C NMR studies of benzocycloalkenes and fluorobenzocycloalkenes, W. Adcock, B.D.Gupta, T.C.Khor and W.Kitching, J.Org. Chem., 41,1976,751-59
  • Substituent effects by 19F NMR: Polar and pi electron effects, W. Adcock, B.D. Gupta and T.C. khor, Aust. J. Chem., 29,1976, 2571-81

Post Doc

  • Regiospecific homolytic displacements in allyl cobaloximes, B.D. Gupta, T. Funabiki and M.D. Johnson, J. Am. Chem. Soc., 98,1976,6697
  • Homolytic displacements at saturated carbon: Synthesis of trichloroethylbenzenes T.Funabiki, B.D.Gupta and M.D.Johnson, Chem.Comm., 1977,763-4
  • Trans influence of anionic, neutral and bridging ligands on NMR spectra, C.Charreton, A.Gaudemer, C.Chapman, B.D.Gupta and M.D.Johnson, J. Chem. Soc. (Dalton) 1978,1807
  • Reactions of allyl and propadienyl Iridium (III) and Rhodium (III) with polyhalogenomethanes, A.E. Crease, B.D. Gupta, M.D. Johnson and S. Moorehouse, J. Chem. Soc. (Dalton), 1978,1821-25
  • Homolytic displacement reactions at carbon centre, A. Bury, C.J. Cooksey, T. Funabiki, B.D. Gupta and M.D. Johnson, J. Chem. Soc.(Perkin 2), 1979,1050-7
  • Homolytic displacement at carbon part 3 A.E.crease, B.D. Gupta, M.D. Johnson, K.N.V. Duong and A. Gaudemer, J. Chem. Soc. (Perkin 2), 1979, 2611-16
  • Formation of allyl and cyclopropropylcarbinyl sulfides in the regiospecific reactions of arene sulfenyl chloride with allyl and butenyl cobaloximes, M.R. Ashcroft, B.D. Gupta and M.D. Johnson, J. Chem. Soc., (Perkin Trans 2) 1980,2021-25
  • Homolytic displacement at carbon part 6 M.R. Ashcroft, A. Bury, A.G. Davies, B.D. Gupta, M.D. Johnson and H. Morris, J. Organometal. Chem., 195,1980,89-104
  • Homolytic displacement at carbon part 4 P. Bougeard, B.D. Gupta and M.D. Johnson, J. Organometal. Chem., 206,1981,211-19

I.I.T. Kanpur

  • Halogenation of thenyl and furyl cobaloximes, B. D. Gupta and S. Roy, Tetrahedron Letter, 1984, 3255-56.
  • Thermal and photochemical reactions of allylcobaloximes with para substituted benzene sulfonyl chlorides, S. Roy and B. D. Gupta, J. Organometal. Chem., 1984, 269, 201-08.
  • NMR spectra of cobaloximes: Unexpected non-equivalence of methyl groups B.D.Gupta and S.Roy, Tetrahedron Letter, 1985, 3609-12
  • Molecular oxygen insertion into picolyl, thenyl, furyl and furfuryl cobaloximes under thermal and photochemical conditions and their decomposition studies, B. D. Gupta and S. Roy, Inorg. Chim. Acta, 1985, 108, 261-64
  • Halogenations of para substituted benzyl cobaloximes part 2 B. D. Gupta and Manoj Kumar, Inorg. Chim. Acta, 1986, 113, 9-12.
  • Regiospecific synthesis of allyl sulfones, B. D. Gupta, S. Roy and S. Sen, Ind. J. Chem., 1985, 24B, 1030-34.
  • Oxidation of benzyl cobaloximes with Mn(III) acetate, M. Roy, Manoj Kumar and B. D. Gupta, Inorg. Chim. Acta, 1986, 114, 87-89.
  • Chemistry of coenzyme B12, B. D. Gupta, Science Reporter, May 1986, 309-13.
  • Homolytic displacement at carbon: First example of alpha attack in the allenyl and propargyl cobaloximes, B. D. Gupta and S. Roy, Tetrahedron Letter, 1986, 27, 4905-08.
  • Homolytic displacement at saturated carbon centre: Synthesis of benzyl sulfones, B. D. Gupta, M. Kumar, Indira Das and M. Roy, Tetrahedron Letter, 1986, 27, 5773-76.
  • Sulphur dioxide insertion into organocobaloximes: A true insertion or a case of radical chain process, B. D. Gupta, M. Roy and S. Roy, Tetrahedron Letter, 1987, 28, 1219-22.
  • Halogenolysis of benzyl cobaloximes, B. D. Gupta and Manoj Kumar, Chemistry Letter, 1987, 701-04.
  • Homolytic displacement at carbon centre, B.D.Gupta, M.D.Johnson, G.M.Lampman and R.W. Koops, J. Organometal. Chem., 1987, 326, 281-88.
  • Homolytic displacement at carbon part 3. First example of alpha attack in the allenyl and propargyl cobaloximes, B. D. Gupta and S. Roy, J. Chem. Soc., (Perkin Trans 2) 1988, 1377-83.
  • Heterolytic cleavage of Co-C bond by thiocyanogen in benzyl cobaloximes part 4 B.D.Gupta and Manoj Kumar, Inorg. Chim. Acta, 1988, 149, 223-27.
  • Organocobaloximes: Cobalt carbon bond stability and synthesis, B. D. Gupta and S. Roy, Inorg. Chim. Acta Review, 1988, 146, 209-21.
  • Halogenation of benzyl and (Heteroaromaticmethyl)cobaloximes: Direct competition between ring halogenation and Co-C bond cleavage, B. D. Gupta , M. Kumar and S. Roy, Inorg. Chem., 1989, 28, 11-13
  • Homolytic displacement at saturated carbon in organocobaloximes part 4 B. D. Gupta, M. Kumar, S. Roy and I. Das, J. Chem. Soc. (Perkin Trans 2), 1990, 537-43
  • Molecular oxygen insertion into organocobaloximes: Kinetic and decomposition studies, B. D. Gupta, M. Roy and I. Das, J. Orgaometal. Chem., 1990, 397, 219-30
  • Heteronuclear NMR studies of cobaloximes: 15N cyanocobalt corrins, B. D. Gupta and K. L. Brown, Inorg. Chem., 1990, 29, 3854-60
  • Halogenation of organocobaloximes: A direct competition between ring halogenation and Co-C bond cleavage part 6, B. D. Gupta and Manoj Kumar, Inorg. Chim. Acta, 1991, 18, 173-79
  • Heteronuclear NMR studies of cobaloximes: Further studies of dicyanocobinamides and the complete proton, carbon and amide nitrogen NMR assignments of di cyano cobalamins, K. L. Brown, H.B. Brooks, B. D. Gupta, Mark Victor, D. C. Scooby, W. J. Goux and R. Timkovitch, Inorg. Chem., 1991, 30, 3430-38.
  • Sulphur dioxide insertion into organocobaloximes: A true insertion or a case of radical process, B. D. Gupta, M. Roy, Moni Oberoi and V. Dixit, J. Organometal. Chem., 1992, 430, 197-204
  • Homolytic displacement at saturated carbon part 5: Synthesis of cyclopropylmethyl, bicyclo[3.1.0]hept-2-yl, Bicyclo[4.1.0]hept-2-yl and cyclohexane spiro-cyclop-2-yl sulfones from the corresponding but-3- enyl cobaloximes, B. D. Gupta, I. Das and V. Dixit, J. Chem. Res.(S) 1992, 306-7, J. Chem. Res. (M) 1992, 2409-46
  • Homolytic displacement at saturated carbon in organocobaloximes: Synthesis of benzyl sulfones part 6 B. D. Gupta, I. Das and V. Dixit, Ind. J. Chem., 1993, 32A 762-66
  • Homolytic displacement at saturated carbon part 7: Synthesis of cyclic, bicyclic and spirocyclic sulfones from the corresponding butenyl cobaloximes with thiophene-2-sulfonyl chloride B. D. Gupta, I. Das and V. Dixit, Ind. J. Chem., 1993, 32A, 1019-22.
  • An efficient SH2 reaction in alicyclic allyl cobaloximes, B. D. Gupta, I. Das, S. Roy and K. Bhanuprakash, Tetrahedron, 50, 1994, 1847-58.
  • Homolytic displacement at carbon in organocobaloximes part 9 Reactions of organocobaloximes with thiophene-2-sulfonyl chloride, B. D. Gupta, and I. Das, Ind. J. Chem., 1996, 35A, 1111-13.
  • Organocobaloximes in organic synthesis: an unusual radical dependent five member cyclization I. Das, S. Chowdhury, K. Ravikumar, B. D. Gupta and S. Roy, J. Organometal. Chem., 1997, 532, 101-07
  • Synthesis of organocobaloximes: Modification of the organic group in organocobaloximes, B. D. Gupta and V. Dixit, J. Organometal. Chem., 1997, 533, 261-64
  • Organobridged dicobaloximes: Synthesis and NMR correlation, B. D. Gupta and Kushal Qanungo, J. Organometal. Chem., 1997, 534, 213-20.
  • A study of cis influence in alkyl cobaloximes, B. D. Gupta and Kushal Qanungo, J. Organometal. Chem., 1997, 543, 127-36.
  • Pyrazine Bridged Organodicobaloximes: A convenient one pot synthesis and cis influence B.D.Gupta, Kushal Qanungo, J. Organometal. Chem., 1998, 557, 243-49.
  • Steric cis influence and Lateral compression of the Metallabicycle in Vit. B12 coenzyme models B. D. Gupta, K. Qanungo, T.M.Barclay and Wally Cordes, J. Organometal. Chem., 1998, 560, 155-61.
  • Studies of cis and trans influence in alkylcobaloximes with different axial bases, B. D. Gupta, Kushal Qanungo, Veena Singh and Shobini, Ind. J. Chem., 1998, 37A, 707-11.
  • Organocobaloximes: synthesis, oxygen insertion and kinetics, B. D. Gupta, V. Vijay Kanth, Veena Singh, J. Organometal. Chem., 1998, 570, 1-7.
  • Co-C bond cleavage in the reactions of alkyl, benzyl and heteroaromaticmethyl cobaloximes with arene sulfenyl chloride: Homolytic and heterolytic pathways, B. D. Gupta, Vandana Dixit and Indira Das, J. Organometal. Chem., 1999, 572, 49-58
  • Homolytic displacement at two reactive centres: Organodicobaloximes and organodisulfonyl chloride, B. D. Gupta, V. Vijay Kanth, Veena Singh, Kushal Qanungo and Raghvendra S Sengar, J. Organometal. Chem., 1999, 582, 279-81,
  • Organocobaloximes with mixed-dioxime equatorial ligands: a one-pot synthesis, B. D. Gupta, V. Singh, K. Qanungo, V. Vijay Kanth, R. Yamuna, T. Barclay and W. Cordes, J. Organometal. Chem., 2000, 602, 1-4.
  • Synthesis, characterisation and cis-trans influence in cobaloximes with nioxime, B. D. Gupta, Kushal Qanungo, R. Yamuna, A. Pandey, Usha Tiwari, V. Vijai Kanth, Veena Singh, T. Barclay and W. Cordes, J. Organometal. Chem., 2000, 608, 106-114.
  • Cleavage of Co-C bond in allyl cobaloximes with arene sulphenyl chloride, B. D. Gupta, V. Dixit, V. Singh and V. Vijai Kanth, Ind. J. Chem., 2000, 39A, 830-834.
  • Homolytic bimolecular displacement at carbon in organocobaloximes: intramolecular cyclizations, B. D. Gupta, V. Vijai Kanth and I. Das, Ind. J. Chem., 2000, 39A, 835-37.
  • Organocobaloximes with mixed-dioxime equatorial ligands: a one-pot synthesis: X-Ray structures of BnCo(dmgH)(dpgH)Py and BnCo(chgH)(dpgH)Py, B. D. Gupta, R. Yamuna, V. Singh , Usha Tiwari, T. Barclay and W. Cordes, J. Organometal. Chem., 2001, 627, 80-92.
  • Inorganic cobaloximes with mixed dioxime equatorial ligands: A convenient one pot synthesis and cis influence studies: Crystal structures of N3Co(dmgH)(dpgH)Py and N3Co(chgH)(dpgH)Py, B. D. Gupta, Usha Tiwari, T. Barclay and W. Cordes, J. Organometal. Chem., 2001, 629, 83-92.
  • Homolytic displacements at carbon in organocobaloximes: Reactions of organocobaloximes with free radical precursor with two radical centres, B. D. Gupta, Moni Oberoi, D. Mandal, Usha Tiwari R. Yamuna, V. Vijai Kanth and Veena Singh, Ind. J. Chem., 2001, 40A, 986-88.
  • Novel synthesis of allyl and cyclopropylcarbinyl thiocyanates by the reaction of organocobaloximes with thiocyanogen, B. D. Gupta, D. Mandal, Vandana Dixit, Ind. J. Chem., 2002, 41A, 970-72.
  • Synthesis, characterisation, cis-trans influence in cobaloximes with glyoxime as the equatorial ligand, B. D. Gupta, R. Yamuna, Veena Singh and Usha Tiwari, Organometallics, 2003, 22, 226-232
  • Organocobaloximes with Mixed Dioxime equatorial Ligands: A Convenient One-Pot Synthesis. X-ray Structures and Cis-Trans Influence Studies, B. D. Gupta, Veena Singh, R. Yamuna, T. Barclay and W. Cordes, Organometallics, 2003, 22, 2670-2678.
  • Reaction of organocobaloximes with aryldisulfonyl chlorides, B. D. Gupta, V. Vijaikanth, J. Organometal. Chem., 2004, 689, 1102-1109.
  • Synthesis characterization and Variable-Temperature 1 H NMR Behavior of Organo-Bridged Dicobaloximes. B. D. Gupta, V. Vijaikanth, Veena Singh, Organometallics, 2004, 23, 2067-2079.
  • Cobaloximes with Dimesitylglyoxime: Synthesis, Characterization, and Spectral Correlations with the Related Cobaloximes, Debaprasad Mandal and B. D. Gupta, Organometallics, 2005, 24, 24,1501-1510.
  • 2-Substituted m-Xylylene Bridged Dicobaloximes: Structure-Property Relationship Using Variable Temperature 1H NMR Study V. Vijaikanth, B. D. Gupta, Debaprasad Mandal and Shashank Shekhar , Organometallics, 24 (2005) 4454-4460.
  • Pyrazine Bridged Benzyl Dicobaloximes: Competition between π-Interaction and Steric   Crowding in Crystal Structure, Debaprasad Mandal and B. D. Gupta, J. Organometal. Chem, 690 (2005) 3746-3754.
  • Cobaloximes with Pyrazine and Their Bimetallic Complexes, Debaprasad Mandal and B. D. Gupta, Eur.J. Inorg. Chem., (2006) 4086–4095.
  • Hindered rotation leading to nonequivalence in cobaloximes, Debaprasad Mandal and B. D. Gupta, Organometallics, 25 (2006) 3305-3307.

·         Cobaloximes with mixed dioximes of glyoxime and diphenylglyoxime: synthesis, characterization, CV, X-ray studies and crystal packing, B. D. Gupta, R. Yamuna and Debaprasad Mandal, Orgaometallics 25 (2006) 706–714

·         Sulfur Dioxide Insertion into Co−C Bond In Organocobaloximes: Crystal Structure And Co−C Bond Reactivity Study, Preeti Chadha, B. D. Gupta and Kingsuk Mahata, Organometallics, 25 (2006) 92–98

  • Hindered rotation leading to nonequivalence in 2-substituted benzyl cobaloximes: Structure-property relationship, Debaprasad Mandal, and B. D. Gupta, Organometallic 27 (2007) 658-670
  • The interaction between axial and equatorial ligands in cobaloximes: NMR changes, Debaprasad Mandal, Preeti Chadha, Moitree Laskar, Mouchumi Bhuyan, B. D. Gupta, Tet. Lett 48 (2007) 2377-2379
  • Co-C Bond reactivity and cis influence relationship in benzylcobaloximes with glyoxime and dimesitylglyoxime. Mouchuni Bhuyan, Moitree Laskar, Debaprasad Mandal, B. D. Gupta, Organometallics (2007)3559.
  • Co-C Bond Homolysis: The Reactivity difference between alkyl and Benzyl cobaloximes. Debaprasad Mandal, Mouchumi Bhuyan, Moitree Laskar, B.D. Gupta, Organometallics (2007) 2795.

 

 

 

 



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