iitkiitkBioinorganic Laboratory
Department of Chemistry
Indian Institute of Technology Kanpur




Dr. Rath's group

From L to R: Front - Bapan, Tapas, Sujit, Sarnali, Sayantani, Dipti, Tamal, Ananda, Akhil

Back - Avinash, Satabdi, Younis, Anjan, Jehanger, Amit, Dr. S. P. Rath, Firoz, Sabyasachi, Ajay, Anjani, Pritam   



  Representative Publications

            1. Silver(III)···Silver(III) Interaction Stabilizes the Syn-form in a Porphyrin Dimer Upon Oxidation

                 A. K. Singh, F. S. T. Khan and S. P. Rath*

                 Angew. Chem. Int. Ed. 2017, 56, 8849-8854


          2. A Highly Oxidized Cobalt Porphyrin Dimer: Spin Coupling and Stabilization of the Four-Electron                                  Oxidation Product

                 S. Dey, D. Sil and S. P. Rath*

                 Angew. Chem. Int. Ed. 2016, 55, 996-1000


            3. Hydrogen Bonding Interactions Trigger a Spin-Flip in Iron(III)-Porphyrin Complexes

                D. Sahoo, M. G. Quesne, S. P. de Visser* and S. P. Rath*

                Angew. Chem. Int. Ed. 2015, 54, 4796-4800

           4. Oxidation Triggers Extensive Conjugation and Unusual Stabilization of Two Di-heme Dication Diradical                  Intermediates: Role of Bridging Group for Electronic Communication

               D. Sil, S. Dey, A. Kumar, S. Bhowmik and S. P. Rath*

               Chem. Sci. 2016, 7, 1212-1223 (EDGE Article) 

            5. A remarkably bent diiron(III)-μ-hydroxo bisporphyrin: Unusual stabilization of two spin states of iron                 in a single molecular framework

                S. K. Ghosh and S. P. Rath*

                J. Am. Chem. Soc. 2010132, 17983-17985



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