S. Dey, D. Sil, Y. A. Pandit and S. P. Rath*

           D. Sahoo, A. K. Singh and S. P. Rath*

         D. Sahoo, T. Guchhait and S. P. Rath*

A series of five-coordinate Fe(III)octaaryltetraphenylporphyrins varying axial ligand field strength and their 1e-oxidized complex have been synthesized and characterized. The molecular structures and their spectroscopic properties including metal spins have been scrutinized.

73.    An Ethane-bridged Porphyrin Dimer as Model of Di-heme Proteins: Inorganic and Bioinorganic Perspectives and Consequences of Heme-Heme Interactions

          D. Sil and S. P. Rath*

A brief account of our recent efforts on how inter-heme interactions can possibly change the structure and functional properties of the individual heme centers in a highly flexible ethane-bridged porphyrin dimer has been presented.

72.    Controlled generation of highly saddled (porphyrinato) iron(III) iodide, tri-iodide and one-electron oxidized complex

          D. Sahoo and S. P. Rath*

Three iron(III) porphyrinato complexes have been isolated selectively just by varying iodine concentration which eventually form admixed-intermediate (iodo complex), pure intermediate (tri-iodide complex) and high-spin (1e-oxidized complex) states of iron where iodide and/or tri-iodide used as axial ligands. Computational calculations clearly support the experimentally assigned spin state.

71.    Metal-coordination-driven Mixed Ligand Binding in Supramolecular Bisporphyrin Tweezers

          Sk. A. Ikbal, A. Dhamija and S. P. Rath*

The mixed ligand polymers of Mg(II)bisporphyrin with heterogeneous guest pairs have been synthesized just by mixing host and guests in one pot and structurally characterized. The guest ligands are bound selectively between inside and outside the bisporphyrin cavity.

70.    Step-wise induction, amplification and inversion of molecular chirality through the coordination of chiral diamines with Zn(II)bisporphyrin

          Sk. A. Ikbal, S. Brahma and S. P. Rath*

A clear structural rationalization of the origin of chirality transfer from an optically active diamine guest to an achiral Zn(II)bisporphyrin host in a 1:1 and 2:3 host-guest supramolecular complex has been demonstrated for the first time. During the process, chirality inversion along with amplification was observed.

69.    Stoichiometry-controlled supramolecular chirality induction in magnesium (II) porphyrin dimer by amino alcohols: mechanistic insights and effect of ligand bulkiness

          S. A. Ikbal, B. Saha and S. P. Rath*

68.    Highly selective and sensitive detection of picric acid explosive by a bisporphyrin cleft: synergistic effects of encapsulation, efficient electron transfer, and hydrogen bonding

          P. Mondal and S. P. Rath*

An efficient host–guest complexation leads to rapid, highly selective, and efficient detection of picric acid (PA) in the presence of other nitroaromatics in solution as well as in the solid phase.

67.    Spin state ordering in hydroxo bridged diiron(III)bisporphyrin complexes

          M. A. Sainna, D. Sil, D. Sahoo, B. Martin, S. P. Rath,* P. Comba* and S. P. de Visser*

We report the synthesis, structure, and spectroscopic characterization of 1,2-bis[μ-hydroxo iron(III) 5-(2,3,7,8,12,13,17,18-octaethylporphyrinyl)]ethane with PF₆^– and SbF₆^– counteranions. The two iron centers are nonequivalent with admixed intermediate spin state (S = 3/2 with a minor contribution of S = 5/2) on each metal both in the solid and in solution. The molecules are compared with previously known μ-hydroxo complexes with other counterions, such as I₃^–, BF₄^–, and ClO₄^–, which demonstrates that the nature of the counterion can affect the spin-state ordering dramatically.

66.    Aggregation-controlled excimer emission in an axial anthracene–Sn(IV)porphyrin–anthracene triad in the solid and solution phases

          S. Dey, P. Mondal and S. P. Rath*

An anthracene-porphyrin donor-acceptor triad has been synthesized and its photophysical properties along with excimer behavior are investigated.

65.    Efficient Host-Guest Complexation of a Bisporphyrin Host with Electron Deficient Guests: Synthesis, Structure and Photoinduced Electron Transfer

          P. Mondal and S. P. Rath*

64.    Axial Thiophenolate Coordination on Diiron(III)bisporphyrin: Influence of Heme-Heme Interactions on Structure, Function and Electrochemical Properties of the Individual Heme Center

          D. Sil, F. S. T. Khan and S. P. Rath*

Synthesis, X-ray structures and properties of a series of diiron(III)bisporphyrin with axial thiophenolate coordination has been reported. The large difference in chemical and electrochemical properties of the dihemes as compared to the monoheme analogs provide an unequivocal evidence of the role played by inter-heme interactions.

63.    Transfer and Control of Molecular Chirality in the 1:2 Host-Guest Supramolecular Complex Consisting of Mg(II) bisporphyrin and Chiral Diols: Effect of H-bonding on Rationalization of Chirality

          Sk. A. Ikbal, S. Brahma and S. P. Rath*

Chiral diol substrate binds to Mg(II)bisporphyrin in an unusual endo-endo fashion due to inter- ligand H-bonding which eventually results in remarkably high amplitude bisignate CD signal.

62.   Highly Enhanced Bisignate Circular Dichroism of Ferrocene-Bridged Zn(II) Bisporphyrin Tweezer with Extended Chiral Substrates due to Well-matched Host-Guest System

          S. Brahma, Sk. A. Ikbal, A. Dhamija and S. P. Rath*

Four new supramolecular chiral tweezer-diamine complexes consisting of an achiral Zn(II)bisporhyrin host (green line) and two small chiral diamines, (1R,2R)-DPEA and (1S,2S)-CHDA, and two large extended chiral diamines, (1R,2R)-DPEApy and (1S,2S)-CHDApy, are reported. Complexes with extended chiral substrates show remarkably high amplitude of bisignate CD signal (blue-line) while smaller substrates show low value (red-line) with opposite sign of CD couplet.

61.    Synthesis, Structure, and Properties of a Series of Chiral Tweezer-Diamine Complexes Consisting of an Achiral Zinc(II) Bisporphyrin Host and Chiral Diamine Guest: Induction and Rationalization of Supramolecular Chirality

          S. Brahma, Sk. A. Ikbal and S. P. Rath*

A series of supramolecular chiral tweezers consisting of an achiral Zn(II)bisporphyrin host and variety of chiral diamine guests have been presented here which demonstrates a full and unambiguous rationalization of the chirality transfer process from the chiral guest to the achiral host observed in many natural and artificial supramolecular assemblies.

60.   Syn-Anti  Conformational Switching in an Ethane-bridged Co(II)bisporphyrin Induced by External Stimuli: Effects of Inter-macrocyclic Interactions, Axial Ligation and Chemical and Electrochemical Oxidations

          S. Dey and S. P. Rath*

The reversible syn-anti conformational switching has been observed either by various external ligands or stepwise oxidations.

59.    Iron(III) and Copper(II) complexes of trans-bis(ferrocenyl)porphyrin: effect of metal ions on long-range electronic communication

           D. Sahoo and S. P. Rath*

58.    Building-up Novel Coordination Polymer with Zn(II) Porphyrin Dimer: Synthesis, Structures, Surface Morphology and Effect of Axial Ligands

          Sk. A. Ikbal, S. Brahma, A. Dhamija and S. P. Rath*

57.    Unusual Stabilization of an Intermediate Spin of Iron upon Axial Phenoxide Coordination on a Diiron(III)bisporphyrin: Effect of Heme-Heme Interactions

           S. Bhowmik, S. Dey and S. P. Rath*

Spin city: Five new phenolate complexes of diiron(III)bisporphyrin, in which 2,4,6-trinitrophenol stabilizes the pure intermediate-spin state (S=3/2) of iron, are reported for the first time. Similar coordination with the corresponding Fe^III monoporphyrin only resulted in stabilization of the high-spin state.

56.    Self-assembly of Cobalt(II) and Zinc(II) Tetranitro Octaethylporphyrin via Bidentate Axial Ligands: Synthesis, Structure, Surface Morphology and Effect of Axial Coordination

          S. Dey, Sk A. Ikbal and S. P. Rath*

55.    Effect of Heme-Heme Interactions and Modulation of Metal Spins by Counter Anions in a Series of Diiron(III)-μ-hydroxo Bisporphyrins: Unusual Stabilization of Two Different Spins in a Single Molecular Framework

          S. K. Ghosh, S. Bhowmik and S. P. Rath*

Anion effect on diiron-bisporphyrin properties: A new family of five ethene-bridged diiron(III)-μ-hydroxo bisporphyrins with the same core structure but different counter anions is reported herein. In these complexes, two different spin states of Fe are stabilized in a single molecular framework.

54.   Supramolecular BODIPY-Zn(II)-Bisporphyrin Dyad and Trinitrofluorenone Encapsulated Triad as Models of Antenna-reaction Center: Synthesis, Structure and Photophysical Properties

          P. Mondal, A. Chaudhary and S. P. Rath*

We describe the synthesis, characterization and photophysical properties of the dyads Zn₂DEP·TNF (1) and Zn₂DEP·2Py-BDP (2) and triad Zn₂DEP·2Py-BDP·TNF (3), which enable us to investigate the changes in the spectroscopic properties upon the axial coordination of 2DEP in the dyads and the further encapsulation of TNF in the triad.

53.   Formation of exo-exo, exo-endo and tweezer conformation induced by axial ligand in a Zn(II) bisporphyrin: Synthesis, structure and property

          A. Chaudhary, Sk. A. Ikbal, S. Brahma and S. P. Rath*

A detailed structural and spectroscopic investigation of axial ligand coordination on Zinc(II)pyrrole-bridged bisporphyrin (Zn₂DEP), have been reported. Our findings demonstrate that the DEP system provides a Pacman pocket with very high vertical and horizontal flexibility that leads to the formation of exo-endo, exo-exo and tweezer complexes of Zn(II)(bisporphyrinato), for the first time in the solid state, depending upon the size and type of axial ligands used.

52.    Switching Orientation of Two Axial Imidazole Ligands between Parallel and Perpendicular in Low-Spin Fe(III) and Fe(II) Nonplanar Porphyrinates

          R. Patra, D. Sahoo, S. Dey, D. Sil and S. P. Rath*

Bis-imidazole-coordinated Fe(III) and Fe(II) porphyrin changes the axial ligand orientation from parallel to perpendicular, respectively, in a nonplanar porphyrinic environment.

51.   Building-up Remarkably Stable Magnesium Porphyrin Polymers Self-assembled via Bidentate Axial Ligands: Synthesis, Structure, Surface Morphology and Effect of Bridging Ligands

          Sk. A. Ikbal, S. Brahma and S. P. Rath*

A series of remarkably stable magnesium porphyrin polymers bridged by large bidentate axial ligands, have been synthesized in one pot in excellent yields and structurally characterized. The surface patterns on HOPG have also been investigated.

50.    Protonation of an oxo-Bridged Diiron Unit Makes Two Iron Centers Different: A New Class of Diiron(III)-μ-hydroxo Bisporphyrin and Control of Spins by Counter Anions

          S. Bhowmik, S. K. Ghosh and S. P. Rath*

The core of the matter: A previously unknown family of diiron(III)-μ-hydroxo bisporphyrins in which two different spin states of Fe are stabilized in a single molecular framework, even though both cores have identical molecular structures, is presented. The spin states were found to be dependent on the counterion.

49.    Induction of Supramolecular Chirality in Di-Zinc(II) Bisporphyrin via Tweezer Formation: Synthesis, Structure and Rationalization of Chirality

           S. Brahma, Sk. A. Ikbal, S. Dey and S. P. Rath*

Two new supramolecular complexes consisting of an achiral bisporphyrin host and a chiral diamine guest are reported. One shows remarkably high amplitude of bisignate CD signal while other one shows very low value.

48.   Encapsulation of TCNQ and Acridinium Ion within Bisporphyrin Cavity: Synthesis, Structure, Photophysical and HOMO-LUMO Gap Mediated Electron Transfer Properties

          A. Chaudhary and S. P. Rath*

Donor-acceptor complexes: Donor–acceptor complexes, which were constructed from free base bisporphyrin (H₄DEP) as a host, strongly encapsulated two electron-deficient guests, TCNQ and the acridinium ion, in its clefts. The extremely low electrochemically evaluated HOMO–LUMO gap in H₄DEP•TCNQ led to facile electron transfer from the host to the guest at room temperature, whilst partial electron transfer took place in [H₄DEP•AcH]ClO₄.

47.    Efficient Complexation of Pyrrole-bridged Di-Zinc(II) Bisporphyrin with Fluorescent Probe Pyrene: Synthesis, Structure, and Photoinduced Singlet-Singlet Energy Transfer

          A. Chaudhary and S. P. Rath*

Fluoroscent guest! : A dizinc(II) bisporphyrin encapsulates the fluorescent probe pyrene (guest) within the bisporphyrin clefts. The solid-state assembly is very robust in solution for days. Spectroscopic studies indicate significant photoinduced singlet–singlet energy transformation from guest to host.

46.     Magnesium inserted porphyrin compound, its blends and devices thereof

           S. S. K. Iyer, S. P. Rath, A. Singh and Sk. A. Ikbal

45.    Control of Spins by Ring Deformation in a Diiron(III)bisporphyrin: Reversal of ClO₄^- and CF₃SO₃^- Ligand Field Strength on the Magnetochemical Series

          S. Bhowmik, S. K. Ghosh and S. P. Rath*

The complete reversal of the ligand field strength between ClO₄^- and CF₃SO₃^- on the ‘magnetochemical’ series is observed in a diiron(III)bisporphyrin. While ClO₄^- gives typical high-spin complex, just by twisting the conformation of the macrocycle shows properties with pure intermediate-spin state with CF₃SO₃^- although the axial ligand strengths suggest the reverse order of spin stabilization.

44.    Axial Phenoxide Coordination on Di-Iron(III)bisporphyrin: Insights from Experimental and DFT Studies

         S. Bhowmik, D. Sil, R. Patra and S. P. Rath*

43.    Syn-anti Conformational Switching: Synthesis and X-ray Structures of Tweezer and Anti Form in a Zinc Porphyrin Dimer Induced by Axial Ligands

          S. Brahma, Sk. A. Ikbal and S. P. Rath*

42.    Models for the Photosynthetic Reaction Center: Synthesis, Structure, and Electrochemical Properties of a Cofacial Di-palladium Bisporphyrin

          A. Chaudhary, R. Patra and S. P. Rath*

41.     Synthesis, Structure and Properties of a High-Spin Fe(III) Porphyrin with Nonequivalent Axial Ligands: Implications for the Hemoproteins

           A. Chaudhary, R. Patra, and S. P. Rath*

40.     A Remarkably Bent Diiron(III)-μ-Hydroxo Bisporphyrin: Unusual Stabilization of Two Spin States of Iron in a Single Molecular Framework

           S. K. Ghosh and S. P. Rath*

A novel diiron(III) bisporphyrin bridged by a single hydroxo group between two Fe-centers is reported in which the Fe-O(H)-Fe angle becomes the smallest ever reported in a Fe-porphyrin and two different spin states of Fe are stabilized in a single molecular framework, for the first time, although both cores have exactly the same chemical entity.

39.     Binding of Catechols to Iron(III) Octaethyl Porphyrin: An Experimental and DFT Investigation

           A. Chaudhury, R. Patra and S. P. Rath*

The synthesis, X-ray structures, and properties of new heme analogues Fe^III(OEP)(L) (L: Hcat, 4-NO₂-Hcat, 4-tBu-Hcat, and sal) are reported, in which catechol binds in an η¹-fashion as an axialligand. Spectroelectrochemical studies of one- and two-electron oxidations are also reported. Experimental findings are supported by DFT calculations.

38.     Effects of Axial Pyridine Coordination in a Saddle-Distorted Porphyrin macrocycle: Stabilization of Hexa-coordinated High-Spin Fe(III) and Air-stable Low-Spin Iron(II) Porphyrinates

            R. Patra, S. Bhowmik, S. K. Ghosh and S. P. Rath*

We have reported here the effect of axial ligand L (L: pyridine/substituted pyridine) on Fe^III(tn-OEP)Cl/Fe^III(tn-OEP)ClO₄ that first form high-spin Fe^III(tn-OEP)(L)₂.X (X: Cl, ClO₄) which, on longer exposure, spontaneously auto reduce to a series of air stable Fe^II(tn-OEP)(L)₂ complexes.

37.      Synthesis, Structure and Photocatalytic Activity of a Remarkably Bent, Cofacial Ethene-linked Diiron(III) μ-oxobisporphyrin

            S. K. Ghosh, R. Patra and S. P. Rath*

A remarkably bent diFe(III)-μ-oxo bisporphyrin with Fe-O-Fe angles of 150.9(2)° is reported in which the bisporphyrin platform ‘open’ and ‘close’ its binding pockets reversibly with very high vertical flexibility. The complex is thermally very inert but undergo prompt photocatalytic oxidation when photolyzed with excess phosphites in benzene under mild condition using aerial oxygen.

36.      Synthesis and Characterization of anti-bisFe(III) Porphyrins, syn-bisFe(III)-μ-oxo Porphyrin and syn-bisFe(III)-μ-oxo Porphyrin Cation Radical

             S. K. Ghosh, R. Patra and S. P. Rath*

BisFe(III) porphyrins containing highly flexible ethane linker are reported in which the bisporphyrin platform ‘open’ and ‘close’ its binding pockets leading to facile syn-anti conformational switching with very high vertical flexibility in a single molecular framework.

35.     Axial Ligand Orientations in a Distorted Porphyrin Macrocycle: Synthesis, Structure and Properties of Low-Spin bis (Imidazole) Fe(III) and Fe(II) porphyrinates

            R. Patra, A. Chaudhary, S. K. Ghosh and S. P. Rath*

Iron(II) and iron(III) tetranitrooctaethylporphyrinates coordinated with two planar and unhindered imidazoles as axial ligand have nearly perpendicular and parallel orientation preferences, respectively, in a nonplanar porphyrinic environment.

34.     Cyanide binding to iron in a highly distorted porphyrin macrocycle: Synthesis and structure of low-spin Fe(II) dicyano porphyrin

            R. Patra and S. P. Rath*

[K(18-crown-6)(H₂O)₂]₂[Fe^II(tn-OEP)(CN)₂] represents the first structurally characterized Fe(II) dicyano porphyrins in a highly distorted macocyclic environment. The metal iron is on the plane of the four porphyrinic nitrogens which are accompanied by the decrease of the saddle distortion with a clear and significant increase in ruffling.

33.      The Effect of Steric Crowding on Porphyrin Conformation and Ring Orientations in a Series of Iron(III) μ-Oxo Dimers Containing meso-Nitrooctaethylporphyrins

            R. Patra, S. Bhowmik, S. K. Ghosh and S. P. Rath* 

32.     Modulation of  metal displacement in a saddle distorted  macrocycle: synthesis, structure and properties of high spin Fe(III) porphyrins and implications for the hemoprotiens

            R. Patra, A. Chaudhary, S. K. Ghosh and S. P. Rath*

A rare family of five and six-coordinated high-spin Fe(III) porphyrins incorporating weak axial ligands are synthesized and structurally characterized which demonstrates, for the first time, step-wise metal displacements in a single distorted macrocyclic environment that has generally been seen in many biological systems.

31. Remarkably Bent, Ethane-Linked, Diiron(III) μ-Oxobisporphyrin: Synthesis, Structure, Conformational Switching, and Photocatalytic Oxidation

          S. K. Ghosh, R. Patra and S. P. Rath*

A remarkably bent bisFe(III)-μ-oxo porphyrin with Fe-O-Fe angles of 147.9(1)º containing highly flexible ethane linker is reported which authenticates, for the first time, the unprecedented ability of the bisporphyrin platform to ‘open’ and ‘close’ its binding pockets leading to facile syn-anti conformational switching with very high vertical flexibility of over 6.5Å in a single molecular framework.

30.   Axial Ligand Coordination in Sterically Strained Vanadyl  Porphyrins: Synthesis, Structure, and Properties

             S. K. Ghosh, R. Patra and S. P. Rath*

A hitherto unknown family of six-coordinate vanadyl porphyrins of the sterically crowded, nonplanar 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetranitroporphyrin incorporating axial ligand L (L: pyridine, THF and MeOH), have been isolated as VO(tn-OEP)(L) in the solid phase for the first time and structurally characterized as shown.

29.      Electronic Structure of the Glyoxalbis(2-hydroxyanil) (gha) Ligand in [Co^III(gha)(PPh₃)₂]⁺: Radical vs. Non-radical States

            A. S. Roy, N. Muresan, H. M. Tuononen, S. P. Rath, P. Ghosh

28.     First Ruthenium Complex of Glyoxalbis(N-phenyl)osazone (LNHPhH₂): Synthesis, X-ray Structure, Spectra, and Density Functional Theory Calculations of (LNHPhH₂)Ru(PPh₃)₂Cl₂

             A. S. Roy, H. M. Tuononen, S. P. Rath, P. Ghosh

27.     Dioxygen Reactivity of Meso-hydroxylated Hemes: Intermediates in Heme Degradation  Process Catalyzed by Heme-oxygenase.

              S. P. Rath*

26.      Electron Distribution in Octaethyloxophlorin Complexes. Importance of the Fe(III) Oxophlorin Trianion Form in the Bis-pyridine and Bis-imidazole Complexes

             S. P. Rath, M. M. Olmstead and A. L. Balch

25.     Metal Complexes of meso-Amino-octaethylporphyrin and the Oxidation of Ni(II)(meso-amino-octaethylporphyrin)

             N. Sprutta, S. P. Rath, M. M. Olmstead and A. L. Balch

24.       Pyramidalization of Gd₃N inside a C80 Cage. The Synthesis and Structure of Gd₃N@C₈₀

             S. Stevenson, J. P. Stevenson, J. E. Reid, M. M. Olmstead, S. P. Rath and A. L. Balch

23.      Oxidative Verdoheme Formation and Stabilization by Axial Isocyanide Ligation

            S. P. Rath, M. M. Olmstead and A. L. Balch

22.     Reaction of Meso-hydroxyhemes with Carbon Monoxide and Reducing Agents in Search  of the Elusive Species Responsible for the g=2.006 Resonance of Carbon Monoxide Treated Heme Oxygenase. Isolation of Diamagnetic Iron(II) Complexes of Octaethyl meso-hydroxyporphyrin

            S. P. Rath, M. M. Olmstead and A. L. Balch

21.      Formation of a Highly Oxidized Iron Biliverdin Complex Upon Treatment of a Five-coordinate Verdoheme with Dioxygen

              K. T. Nguyen, S. P. Rath, L. Latos-Grazynski, M. M. Olmstead and A. L. Balch

20.      The Effect of Axial Ligands on Spin States and Electron Distribution in Iron Complexes of Octaethyloxophlorin, Intermediates in Heme Degradation

              S. P. Rath, M. M. Olmstead and A. L. Balch

19.       A Novel Pentacoordinated Dioxovanadium(V) Salicylaldiminate: Solvent Specific Crystalisation of Dimorphs with Contrasting Coordination Geometries, Ligand Conformations and Supramolecular Architectures 

              B. Baruah, S. P. Rath and A. Chakravorty

18.       Facile Ring Opening of Iron(III) and Iron (II) Complexes of meso-Amino-octaethylporphyrin by Dioxygen

              S. P. Rath, H. Kalish, L. Latos-Grazynski, M. M. Olmstead and A. L. Balch

17.        Formation and Isolation of an Iron-Tripyrrole Complex from Heme Degradation

              S. P. Rath, M. M. Olmstead, L. Latos-Grazynski and A. L. Balch

16.       Reversible Binding of Nitric Oxide and Carbon-Carbon Bond Formation in a Meso-Hydroxylated Heme

             S. P. Rath, R. Koerner, M. M. Olmstead and A. L. Balch

15.       Heme Cleavage with Remarkable Ease: Paramagnatic Intermediates Formed by Aerial Oxidation of a Meso-Amino-Substituted Iron Porphyrin

             H. Kalish, H. M. Lee, M. M. Olmstead, L. Latos-Grazynski, S. P. Rath and A. L. Balch

14.        Synthesis, structure and properities of mononuclear oxovanadium(V) alkoxides incorporating chelated ethane-1,2-diol and propane-1,3-diol

              K. K. Rajak, S. Mondal and S. P. Rath

13.        Sugar Binding to VO³⁺. Synthesis and Structure of a New Mannopyranoside Vanadate

              K. K. Rajak, B. Baruah, S. P. Rath and A. Chakravorty

12.        Ruthenium dithiophosphates: Synthesis, X-ray crystal structure, spectroscopic and electrochemical properties

               P. U. Jain, P. Munshi, M. G. Walawalkar, S. P. Rath, K. K. Rajak and G. K. Lahiri

11.      Synthesis, Structure and Catecholase Reaction of a Vanadate Ester System  Incorporating Monoionized Catechol Chelation

               S. P. Rath, K. K. Rajak and A. Chakravorty

10.       Carbohydrate Binding to VO³⁺. Sugar Vanadate Esters Incorporating L-Amino Acid Schiff Bases as Coligands

              K. K. Rajak, S. P. Rath, S. Mondal and A. Chakravorty

9.        Sugar vanadates: synthesis and characterisation of mannopyranoside and ribofuranoside esters incorporating VO³⁺

             K. K. Rajak, S. P. Rath, S. Mondal and A. Chakravorty

8.          Sugar vanadates : Synthesis and characterisation of a mannopyranoside ester  incorporating  VO³⁺

              K. K. Rajak, S. P. Rath, S. Mondal and A. Chakravorty

7.           A Family of (N-Salicylidene-a-aminoacidato)Vanadate Esters Incorporating Propane-1,3-diol and Glycerol: Synthesis, Structure and Reaction

              S. Mondal, S. P. Rath, K. K. Rajak and A. Chakravorty

6.          Synthesis and Structure of Vanadate Esters of Glycerol and Propane-1,3-diol

              S. P. Rath, K. K. Rajak, S. Mondal and A. Chakravorty

5.          Chemistry of Hydrazonato Oxovanadium(V) Alkoxides Derived from Dihydric/ Monohydric Alkohols

              S. P. Rath, S. Mondal and A. Chakravorty

4.          Synthesis, Structure and Metal Redox of Alkoxide Bound Oxovanadium(V) Complexes Incorporating N-salicylidene/N-naphthalidene-a-aminoalcohols

              S. P. Rath, T. Ghosh and S. Mondal

3.          Chemistry of Oxovanadium(V) Alkoxides: Synthesis and Structure of Mononuclear Complexes Incorporating Ethane-1,2-diol

               S. Mondal, S. P. Rath, S. Dutta and A. Chakravorty

2.           Mixed-Ligand Oxovanadium(V) Complexes Incorporating Bidentate Salicylaldehyde and Tridentate Aldimine Ligands

               S. P. Rath, S. Mondal and T. Ghosh

1.           Water Soluble Mixed-Ligand Oxovanadium(IV) Complexes of Acetylacetone and Aldimine  Ligands

               S. P. Rath, S. Mondal and T. Ghosh