Bioinorganic Laboratory
Department of Chemistry
Indian Institute of Technology Kanpur
Prof. Rath's group
From L to R: Front- Sayantani, Niva, Chandrani, Deepannita, Paulami, Dolly, Namrata, Back- Subhadip, Santanu, Arya, Prof. S. P. Rath, Anindya, Jehanger, Sabyasachi, Nityananda, Nidhi.
Representative Publications
1. Modulation of Supramolecular Chirality by Stepwise Axial Coordination in a Nano-size Trizinc(II)
porphyrin Trimer
A. Dhamija, D. Chandel and S. P. Rath*
Chem. Sci., 2023, 14, 6032-6038 (EDGE Article)
2. Cooperativity in Diiron(III)porphyrin Dication Diradical-Catalyzed Oxa-Diels-Alder Reactions:
Spectroscopic and Mechanistic Insights
S. Sarkar, P. Sarkar, D. Samanta, S. K. Pati and S. P. Rath*
ACS Catal. 2022, 12, 9589-9601
3. Silver(III)···Silver(III) Interaction Stabilizes the Syn-form in a Porphyrin Dimer Upon Oxidation
A. K. Singh, F. S. T. Khan and S. P. Rath*
Angew. Chem. Int. Ed. 2017, 56, 8849-8854
4. A Highly Oxidized Cobalt Porphyrin Dimer: Spin Coupling and Stabilization of the Four-Electron Oxidation Product
S. Dey, D. Sil and S. P. Rath*
Angew. Chem. Int. Ed. 2016, 55, 996-1000
5. Hydrogen Bonding Interactions Trigger a Spin-Flip in Iron(III)-Porphyrin Complexes
D. Sahoo, M. G. Quesne, S. P. de Visser* and S. P. Rath*
Angew. Chem. Int. Ed. 2015, 54, 4796-4800
6. Oxidation Triggers Extensive Conjugation and Unusual Stabilization of Two Di-heme Dication Diradical Intermediates: Role of Bridging Group for Electronic Communication
D. Sil, S. Dey, A. Kumar, S. Bhowmik and S. P. Rath*
Chem. Sci. 2016, 7, 1212-1223 (EDGE Article)
7. A remarkably bent diiron(III)-μ-hydroxo bisporphyrin: Unusual stabilization of two spin states of iron in a single molecular framework
S. K. Ghosh and S. P. Rath*
J. Am. Chem. Soc. 2010, 132, 17983-17985
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